CHM 2046C Module 11 – Chapter 17 Sample Exam

Part E: Equilibria of Acids and Bases Calculations       10 points

Write the appropriate equilibrium constant expression for the following reaction::

 

A solution prepared from 0.055 mol of butanoic acid dissolved in sufficient water to give 1.0 L of solution has a pH of 2.72.  Determine Ka for butanoic acid.  The acid ionizes at according to the balanced equation.

CH3CH2CH2CO2H(aq)   +   H2O   ó    H3O+1    +   CH3CH2 CH2CO2-1(aq)

 

 

[CH3CH2 CH2CO2H]

[H3O+1]

[CH3CH2 CH2CO2-1]

Initial

 

 

 

Change

 

 

 

Equilibrium

 

 

 

 

 

 

 

 

 

What are the equilibrium concentrations of acetic acid, the acetate ion, and hydronium ion for a 0.10 M solution of acetic acid (Ka = 1.8 x 10-5)?  What is the pH of the solution?

Ionization Reaction(you write):

 

 

   [CH3CO2H]

         [H3O+1]

      [CH3CO2-1]

Initial

 

 

 

Change

 

 

 

Equilibrium

 

 

 

 

 

 

 

 

 

Part F: Hydrolysis Calculations       10 points

What is the pH of the bleach solution which is 5.25% by weight Sodium hypochlorite, NaClO?

The  Ka of   Hypochlorous acid is 3.5 x 10-8