CHM 2046C    Module 14 Pretest#1  Name: __Sample_____

 

Part G: Electrochemical Determination of pH  10 points

                                                                                            

 

Nernst Equation:

 E = Eo – RT/nF [ln Q]        or         E = Eo - 2.303RT/nF [log Q]

 

Or E = Eo – 0.0592 V/n [log Q]      in volts at 25oC

 

Standard Cell Potential and the Equilibrium Constant:

 Eo =0.0593 V/n [log K] in volts at 25oC

 

R = 8.31451 J / K∙mol  F = Faraday Constant = 9.6485309 x 104 J/V∙mol

 

Worked Example 17.8

 

Worked Example from Another text: