CHM 2046C                                         Sample Exam Answers               

 

Module Eight Part II: Solutions Chapter 14

   

Part P: Enthalpy of Solution Calculation    4 point

        

Use the following data to calculate the enthalpy of solution of sodium perchlorate, NaClO4:

               Hºf (s) = -382.9 kJ/mol

               Hºf (aq, 1 m) = -369.5 kJ/mol

 

The solution process of   NaClO4 (s);

 

NaClO4 (s) à  NaClO4 (aq, 1 m)

 

Hºsolution = ∑ [∆Hºf (product) ] - ∑ [∆Hºf (reactant) ]

 

Hºsolution =  Hºf (aq, 1 m) - ∆Hºf (s)

 

Hºsolution =  (-369.5 kJ/mol) – (-382.9 kJ/mol)

 

Answer:

Hºsolution =  13.4 kJ/mol

 

 

 

 

 

 

See Example 14.3 p668-669

 

Work Example 14.3 p 669

 

Similar Problems:  Kotz Chapter 14  p693 #13-20